Here's all items with a custom/modified "head" display render thing, as of 1.21.10.
The "template" stuff is for multiple variants.
1.21.10\assets\minecraft\models\block\*.json
calibrated_sculk_sensor
faces the purple bit forwards


"head": {
"rotation": [ 0, -180, 0 ],
"translation": [ 0, 0, 0 ],
"scale": [ 1, 1, 1 ]
}end_rod
unicorn


"head": {
"rotation": [ -60, 0, 0 ],
"translation": [ 0, 5, -9],
"scale":[ 1, 1, 1]
}stairs


"head": {
"rotation": [ 0, -90, 0 ],
"translation": [ 0, 0, 0 ],
"scale": [ 1, 1, 1 ]
}template_campfire
campfire doesn't actually have a model, but we can see what it would look like using vanilla tweak's 3d models resource pack.
possibly from 19w02a when campfires didn't have an item texture?


"head": {
"translation": [ 0, 10.5, 0 ]
}campfire_off
i believe this is impossible to see, possibly left over from before we had soul campfires?
"head": {
"rotation": [ 0, 0, 0 ],
"translation": [ 0, 10.5, 0 ],
"scale":[ 1, 1, 1 ]
}template_custom_fence_gate


"head": {
"translation": [0, -3, -6]
}template_fence_gate
"head": {
"rotation": [ 0, 0, 0 ],
"translation": [ 0, -3, -6],
"scale":[ 1, 1, 1]
}template_lightning_rod


"head": {
"rotation": [ -180, 0, 0 ],
"translation": [ 8.5, 4, 0 ]
}1.21.10\assets\minecraft\models\item\*.json
amethyst_bud
moved to front






"head": {
"translation": [ 0, 14, -5 ]
}amethyst_cluster


"head": {
"translation": [ 0, 14, -5 ]
}bone
bone in mouth


"head": {
"rotation": [ 0, 0, -45 ],
"translation": [ 0, -4.5, -6.5],
"scale":[ 1, 1, 1 ]
}cod
fish slap


"head": {
"rotation": [ 0, 90, -60 ],
"translation": [ -7, -4, -7],
"scale":[ 0.8, 0.8, 0.8]
}conduit
pointless, its hidden in the head


"head": {
"rotation": [ 0, 180, 0 ],
"translation": [ 0, 0, 0],
"scale":[ 1, 1, 1]
}decorated_pot
pot on head


"head": {
"rotation": [ 0, 180, 0 ],
"translation": [ 0, 16, 0],
"scale":[ 1.5, 1.5, 1.5 ]
}feather
feather pointing up


"head": {
"rotation": [ 0, 0, 45 ],
"translation": [ -1, 13, 7],
"scale":[ 1, 1, 1]
}lead
monacle


"head": {
"rotation": [ 0, 0, 0 ],
"translation": [ 2.75, -2.75, -6.5],
"scale":[ 0.8, 0.8, 0.8]
}spyglass_in_hand
funny spyglass


"head": {
"rotation": [90, 0, 0],
"translation": [0, 0, -16],
"scale": [1.6, 1.6, 1.6]
}template_banner
banner on head


"head": {
"rotation": [ 0, 180, 0 ],
"translation": [ 0, 16, 7],
"scale":[ 1.5, 1.5, 1.5 ]
}template_bed


"head": {
"rotation": [ 0, 180, 0 ],
"translation": [ 0, 10, -8 ],
"scale": [ 1, 1, 1 ]
}template_chest
face chest forward


"head": {
"rotation": [ 0, 180, 0 ],
"translation": [ 0, 0, 0],
"scale":[ 1, 1, 1]
}template_copper_golem_statue
copper statue facing forward, on head, flipped correctly


"head": {
"rotation": [ 0, 180, 180 ],
"translation": [ 0, 22.5, 0 ],
"scale": [ 1, 1, 1 ]
}template_shulker_box
shulker box facing forward (basically pointless)


"head": {
"rotation": [ 0, 180, 0 ],
"translation": [ 0, 0, 0],
"scale":[ 1, 1, 1]
}